Transesterification Reactions Catalyzed by Subtilisins
نویسندگان
چکیده
منابع مشابه
Transesterification reactions catalyzed by chymotrypsin.
As recently reported, the behavior of acetyl chymotrypsin with ethanol consists in a rapid transfer of the single acetyl group to that alcohol with the formation of ethyl acetate (1). Thus, the splitting of nitrophenyl acetates by chymotrypsin, faster in ethanolic than in aqueous solutions, may be explained by the formation of acetyl chymotrypsin as an intermediate and its subsequent preferenti...
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The hydrolysis of a series of esters of benzoyl-L-arginine and glycylglycine by papain has been examined in mixtures of water with various alcohols in the pH range of 5 to 6. The presence of straight chain alcohols resulted in an apparent inhibition of acid release. It was shown that this inhibition could, in part, be accounted for by papain-catalyzed transesterification reactions between the v...
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The transesterification process of trimethylphosphate with ethanol and isopropanol is examined. It is found that the reaction does not proceed in the absence of base even at temperature up to 100°C, whereas in the presence of sodium alkoxide as a catalyst it takes place at room temperature leading to a mixture of mono-,bi-, tri-substitute esters as well as the minor by-products resulting from t...
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the transesterification process of trimethylphosphate with ethanol and isopropanol is examined. it is found that the reaction does not proceed in the absence of base even at temperature up to 100°c, whereas in the presence of sodium alkoxide as a catalyst it takes place at room temperature leading to a mixture of mono-,bi-, tri-substitute esters as well as the minor by-products resulting from t...
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The synthesis of L-ascorbyl flurbiprofenate was achieved by esterification and transesterification in nonaqueous organic medium with Novozym 435 lipase as biocatalyst. The conversion was greatly influenced by the kinds of organic solvents, speed of agitation, catalyst loading amount, reaction time, and molar ratio of acyl donor to L-ascorbic acid. A series of solvents were investigated, and ter...
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ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1966
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(18)96885-7